全文获取类型
收费全文 | 6170篇 |
免费 | 1266篇 |
国内免费 | 973篇 |
专业分类
化学 | 4485篇 |
晶体学 | 186篇 |
力学 | 369篇 |
综合类 | 99篇 |
数学 | 689篇 |
物理学 | 2581篇 |
出版年
2024年 | 3篇 |
2023年 | 107篇 |
2022年 | 170篇 |
2021年 | 240篇 |
2020年 | 314篇 |
2019年 | 345篇 |
2018年 | 278篇 |
2017年 | 321篇 |
2016年 | 385篇 |
2015年 | 409篇 |
2014年 | 458篇 |
2013年 | 606篇 |
2012年 | 687篇 |
2011年 | 636篇 |
2010年 | 496篇 |
2009年 | 488篇 |
2008年 | 474篇 |
2007年 | 383篇 |
2006年 | 310篇 |
2005年 | 273篇 |
2004年 | 218篇 |
2003年 | 155篇 |
2002年 | 128篇 |
2001年 | 104篇 |
2000年 | 64篇 |
1999年 | 73篇 |
1998年 | 33篇 |
1997年 | 43篇 |
1996年 | 46篇 |
1995年 | 45篇 |
1994年 | 20篇 |
1993年 | 23篇 |
1992年 | 12篇 |
1991年 | 13篇 |
1990年 | 11篇 |
1989年 | 9篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1986年 | 3篇 |
1985年 | 7篇 |
1984年 | 2篇 |
1983年 | 5篇 |
1982年 | 2篇 |
1980年 | 4篇 |
1936年 | 2篇 |
排序方式: 共有8409条查询结果,搜索用时 21 毫秒
51.
Dr. Malin Li Dr. Yu Gao Dr. Nan Chen Dr. Xing Meng Prof. Chunzhong Wang Dr. Yaoqing Zhang Dr. Dong Zhang Prof. Yingjin Wei Dr. Fei Du Prof. Gang Chen 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(32):11405-11412
Cu3V2O8 nanoparticles with particle sizes of 40–50 nm have been prepared by the co‐precipitation method. The Cu3V2O8 electrode delivers a discharge capacity of 462 mA h g?1 for the first 10 cycles and then the specific capacity, surprisingly, increases to 773 mA h g?1 after 50 cycles, possibly as a result of extra lithium interfacial storage through the reversible formation/decomposition of a solid electrolyte interface (SEI) film. In addition, the electrode shows good rate capability with discharge capacities of 218 mA h g?1 under current densities of 1000 mA g?1. Moreover, the lithium storage mechanism for Cu3V2O8 nanoparticles is explained on the basis of ex situ X‐ray diffraction data and high‐resolution transmission electron microscopy analyses at different charge/discharge depths. It was evidenced that Cu3V2O8 decomposes into copper metal and Li3VO4 on being initially discharged to 0.01 V, and the Li3VO4 is then likely to act as the host for lithium ions in subsequent cycles by means of the intercalation mechanism. Such an “in situ” compositing phenomenon during the electrochemical processes is novel and provides a very useful insight into the design of new anode materials for application in lithium‐ion batteries. 相似文献
52.
Cover Picture: One‐Step Synthesis of Silver Nanoparticle‐Decorated Hydroxyapatite Nanowires for the Construction of Highly Flexible Free‐Standing Paper with High Antibacterial Activity (Chem. Eur. J. 32/2016) 下载免费PDF全文
53.
明胶空心胶囊样品经硝酸微波消解,采用石墨炉原子吸收光谱法测定其中铬的残留量。采用灰化温度为900℃,原子化温度为2 500℃。铬的质量浓度在2~30μg·L-1范围内与其吸光度呈线性关系,检出限(3s/k)为0.103mg·kg-1。应用此方法分析了明胶空心胶囊样品。用标准加入法进行回收试验,所得回收率在95.9%~102%之间,测定值的相对标准偏差(n=9)均小于2.0%。 相似文献
54.
55.
A new 19-oxygenated steroid, 25-acetate-nebrosteroid K (1), and five known steroids (2–6), along with one known 19-hydroxy steroidal glycoside (7) were obtained from the gorgonian Dichotella gemmacea collected from the South China Sea. The structure and relative configuration of 1 were elucidated by using comprehensive spectroscopic data including NOESY spectra. Compound 1 represents the first example of 19-oxygenated steroid with a 19-oic acid methyl ester group isolated from gorgonians. All of the isolated compounds were evaluated for lethal activity to brine shrimp Artemia salina and cytotoxicity against A549 and HL-60 cell lines. Among them, 1 showed strong lethality towards A. salina. 相似文献
56.
Gang-Gang Bai Fei Yuan Fu-Qiang Li Kun-Jun Mao Ping Zhou 《Natural product research》2015,29(15):1481-1484
This article reports the lipophilic chemical composition of different processed products (Changii Radix, Changii Radix Alba) and parts (root bark, leaf and fruit) of Changium smyrnioides Wolff.. The lipophilic constituents were extracted with petroleum ether in Soxhlet apparatus, subsequently identified and determined by gas chromatography–mass spectroscopy (GC–MS). Yield of lipophilic constituents from Changii Radix (3.65%) was about three times more than Changii Radix Alba's (1.07%), which indicated processing by boiling in water had an impact on the content of lipophilic constituents. Moreover, the major compounds in different processed products and parts were found to be fatty acids and sesquiterpenes. The results are a contribution for the lipophilic chemical composition and can serve as a reference for product development of Changium smyrnioides Wolff.. 相似文献
57.
Conjugated microporous polymers (CMPs) have recently received extensive attention in oil/organic solvent-water separation field as a kind of ideal porous absorbents with tunable porosity, large surface areas, and super-hydrophobicity. However, reports on the application of CMPs in adsorption of hydrophilic contaminants from water are very few. In this work, we studied the adsorption of metronidazole (MNZ), a polar antibiotic, by two kinds of CMPs. The adsorption characteristics of MNZ by the CMPs, including adsorption kinetics, mechanism, and isotherm parameters were calculated. The adsorption kinetics of MNZ was well expressed by the pseudo-second-order model, and the adsorption process was found to be mainly controlled by film diffusion. The adsorption isotherm data agreed well with the Langmuir isotherm model, and the values of free energy E indicated that the adsorption nature of MNZ on the CMPs was physisorption. Increasing dispersion degree of the CMPs in MNZ solution resulted in greater adsorption. This work may provide fundamental guidance for the removal of antibiotics by CMPs. 相似文献
58.
Preparation and Electrochemical Properties of Tin–Iron–Carbon Nanocomposite as the Anode of Lithium‐Ion Batteries 下载免费PDF全文
Dr. Xu Yang Dr. Rongyu Zhang Dr. Xiaofei Bie Prof. Chunzhong Wang Malin Li Dr. Nan Chen Prof. Yingjin Wei Prof. Gang Chen Dr. Fei Du 《化学:亚洲杂志》2015,10(11):2460-2466
Tin–iron–carbon nanocomposite is successfully prepared by a sol–gel method followed by a chemical vapor deposition (CVD) process with acetylene gas as the carbon source. The structural properties, morphology, and electrochemical performances of the nanocomposite are comprehensively studied in comparison with those properties of tin–carbon and iron–carbon nanocomposites. Sheet‐like carbon architecture and different carbon contents are induced thanks to the catalytic effect of iron during CVD. Among three nanocomposites, tin–iron–carbon demonstrates the highest reversible capacity of 800 mA h g?1 with 96.9 % capacity retention after 50 cycles. It also exhibits the best rate capability with a discharge capacity of 420 mA h g?1 at a current density of 1000 mA g?1. This enhanced performance is strongly related to the carbon morphology and content, which can not only accommodate the large volume change, but also improve the electronic conductivity of the nanocomposite. Hence, the tin–iron–carbon nanocomposite is expected to be a promising anode for lithium‐ion batteries. 相似文献
59.
In this paper, we establish the existence of three weak solutions for quasilinear elliptic equations in an Orlicz-Sobolev space via an abstract result recently obtained by Ricceri in [13]. 相似文献
60.
On the decay and blow‐up of solution for coupled nonlinear wave equations with nonlinear damping and source terms 下载免费PDF全文
In this work, we consider a nonlinear coupled wave equations with initial‐boundary value conditions and nonlinear damping and source terms. Under suitable assumptions on the damping terms and source terms and initial data in the stable set, we obtain that the decay estimates of the energy function is exponential or polynomial by using Nakao's method. By using the energy method, we obtain the blow‐up result of solution with some positive or nonpositive initial energy. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献